ANALYSIS OF THERMAL BEHAVIOUR OF UNDOPED AND DOPED CADMIUM SULPHIDE NANOMATERIALS FOR ENERGY APPLICATIONS
DOI:
https://doi.org/10.63458/ijerst.v1i1.58Keywords:
Cadmium Sulphide, Chemical Precipitation, XRD, TGA, DSCAbstract
Undoped Cadmium sulphide and doped cadmium sulphide nanomaterials with copper and silver are effectively synthesized using ethylene glycol as a capping agent by the chemical precipitation process. Scanning electron microscopy and x-ray diffraction studied the composition and crystalline structure of materials. These techniques have estimated the average particle size of such nanomaterials to be between 4-8 nm. Energy Analysis Dispersive X-Ray reveals the components present in these materials. Using UV-visible absorption spectrums, the nanoparticles were calculated in the band gap, resulting in significantly blue values being moved from the large Cadmium Sulphide Band Gap values. The thermal properties of the nanomaterials were analysed by Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC).
References
Edwin, Aboje, Ubieko., J.A., Amusan., Evelyn, Osarolube., C.U., Okujagu. (2023). Potential of Hawleyite Cadmium
Sulphide (CdS) Nanofilms for PV Cell Applications. Journal of Energy Research and Reviews, doi:
9734/jenrr/2023/v13i3266
J., Spencer, George., VS, Lekha., G., Rathika, Nath., Kota, Rajesh. (2022). Cadmium sulphide nanoparticles from Cadmium (II) complex of (Cyclododecylidineamino)thiourea. doi: 10.1088/1757-899X/1263/1/012011
Aqsa, Rafique., Muhammad, Ikram., Ali, Haider., Anwar, Ul-Hamid., Sadia, Naz., Walid, Nabgan., Junaid, Haider., I., Shahzadi. (2022). Dye degradation, antibacterial activity and molecular docking analysis of cellulose/polyvinylpyrrolidone-doped cadmium sulphide quantum dots.. International Journal of Biological Macromolecules, doi: 10.1016/j.ijbiomac.2022.06.058
O, Okorie., Ada, Buba. (2023). Studies on the Optical Dispersion Parameters and Electronic Polarizability of Cadmium Sulphide Thin Film. Asian Journal of Research and Reviews in Physics, doi: 10.9734/ajr2p/2023/v7i2134
J.R., Jayaramaiah., V., Jayanth., R., Shamanth. (2020). Structural elucidation and optical analysis on europium doped cadmium sulphide nano thin films. Optik, doi: 10.1016/J.IJLEO.2019.164079
Sivanand R., Chellammal S and Manivannan S (2019) “Synthesis, Structural Analysis of Cadmium Sulphide Nanocrystallites” in Materials Science Forum ISSN: 1662-9752, vol. 969, pp. 169-174
Sivanand R., Chellammal S and Manivannan S (2019) “Impedance spectroscopy studies of Silver Doped Cadmium Sulphide Nanocrystallites” in IOP Conf. Series: Materials Science and Engineering 310,2018, 012001 doi:10.1088/1757-899X/310/1/012001
S. Muruganandam, G. Anbalagan, G. Murugadoss “Synthesis and structural, optical and thermal properties of CdS:Zn2+ nanoparticles” in Appl Nanosci , vol 4, pp. 1013–1019, 2014. DOI 10.1007/s13204-013-0284-z
Sivanand R., Chellammal S and Manivannan S (2018) “Cadmium Sulphide Nanocrystallites for Optoelectronic Devices” in Materials Science Forum ISSN: 1662-9752, vol. 969, pp. 237-241
M. Tamborra, M. Striccoli, R. Comparelli, M. L. Curri, A. Petrella, and A. Agostiano, “Optical properties of hybrid composites based on highly luminescent CdS nanocrystals in polymer,” Nanotechnology, vol. 15 (4), pp. S240–S244, 2004.
JejenijaOsuntokun and Peter A. Ajibade “Structural and Thermal Studies of ZnS and CdS Nanoparticles in Polymer Matrices” in Journal of Nanomaterials , 2016, http://dx.doi.org/10.1155/2016/3296071
Murugadoss G “Synthesis and study of optical and thermal properties of multi layers coated CdS core–shell nanocomposites”. J Lumin vol.146, pp. 430–434, 2014.
N. Soltani, E. Saion, W. M. M. Yunus et al., “Photocatalytic degradation of methylene blue under visible light using PVPcapped ZnS and CdS nanoparticles,” Solar Energy, vol. 97, pp. 147–154, 2013.